2025年10月8日 星期三

金屬有機骨架實驗 開發一種將金屬和有機分子結合在一起的新型分子結構。金屬充當節點,並透過含碳的有機分子連接起來。這些結構內部形成巨大的空隙,氣體和其他物質可以透過這些空隙流通。

 金屬有機骨架實驗  開發一種將金屬和有機分子結合在一起的新型分子結構。金屬充當節點,並透過含碳的有機分子連接起來。這些結構內部形成巨大的空隙,氣體和其他物質可以透過這些空隙流通。

The scientists are responsible for developing a new kind of molecular structure that combined metals and organic molecules. The metals act as nodes and are linked up by organic molecules containing carbon. Large, empty spaces form inside these structures through which gases and other materials can flow through.

Dr. Robson first experimented with metal-organic frameworks in 1989, when he combined copper ions with four-armed molecules, the committee said. The result was a sort of crystal with large cavities, indicating that other molecules might be able to move in and out of the framework easily.

But the structure was unstable and collapsed quickly. That initial experiment was built on by Dr. Kitagawa and Dr. Yaghi, whose work from 1992 to 2003 helped stabilize the framework that Dr. Robson had created, the committee said.

諾貝爾委員會為何稱他們獲獎?

這些科學家負責開發一種將金屬和有機分子結合在一起的新型分子結構。金屬充當節點,並透過含碳的有機分子連接起來。這些結構內部形成巨大的空隙,氣體和其他物質可以透過這些空隙流通。


委員會表示,羅布森博士於1989年首次進行了金屬有機骨架實驗,當時他將銅離子與四臂分子結合在一起。實驗結果形成了一種具有大空腔的晶體,這表明其他分子可能能夠輕鬆地進出該骨架。


但這種結構不穩定,很快就會坍塌。委員會表示,北川博士和矢吉博士在最初的實驗基礎上進行了改進,他們在1992年至2003年期間的工作幫助穩定了羅布森博士創建的骨架。


林克博士將這種結構比喻為《哈利波特》系列中妙麗‧格蘭傑所使用的手提包。這個袋子外表看起來很小,但內部空間卻很大,可以容納更大的東西。


這位科學家的實驗為數千種金屬有機結構的開發奠定了基礎,這些結構在現實世界中有著廣泛的應用,例如捕獲水果釋放的氣體,使其成熟得更慢。


倫敦帝國學院的計算化學家金·傑爾夫斯(Kim Jelfs)表示,這「激發了一個全新的領域」。 「現在有很多人在這個領域工作,」她說。


在化學中,分子會以不可預測的結構排列。傑爾夫斯博士說,科學家們能夠將金屬和有機分子組合成“構建塊”,這樣即使簇的大小發生變化,你仍然可以獲得相同的結構,但內部的空腔更大。


她說,在化學領域,這種程度的控制「一直是個挑戰」。 “所以這也是令人興奮的一部分。”


Dr. Linke likened the structure to the handbag used by the character Hermione Granger in the “Harry Potter” series. The bag looks small on the outside, but has space on the inside to fit larger stuff.

The scientist’s experiments laid the foundation for the development of thousands of metal-organic structures with many real-world applications, like trapping gas emitted by fruit so it ripens more slowly.


It “has “sparked a whole field,” said Kim Jelfs, a computational chemist at Imperial College London. “There’s an enormous number of people that work in this area now,” she said.

In chemistry, molecules arrange themselves in unpredictable structures. The scientists were able to combine metals and organic molecules as “building blocks,” so that even if the size of the clusters change, you would still get the same structure but with larger cavities inside, Dr. Jelfs said.

That level of control within chemistry has “always been a challenge,” she said. “So that’s part of the excitement.”

2025年9月18日 星期四

小號鉍晶體 CHIP 據說比 INTEL 公司的晶片 40 %更快 10% 省電

 



小號鉍晶體

鉍 (Bi) 是一種重而脆的後過渡金屬,原子序數為 83,是唯一無毒的重金屬。它被用於治療消化問題的非處方藥 Pepto-Bismol,作為合金和其他產品中鉛的無毒替代品,以及化妝品和電子產品。鉍具有獨特的銀白色金屬光澤和虹彩般的光澤,通常是鉛礦石加工的副產品。

關鍵特性

化學符號:Bi

原子序數:83

物理外觀:一種脆性的銀白色金屬,具有金屬光澤和虹彩般的光澤。

密度:比鉛重。

毒性:唯一無毒的重金屬。

熔點:與其他金屬相比,其熔點相對較低。

導電性:金屬的熱導率和電導率異常低。

用途

醫藥:用於治療消化不良、腹瀉和潰瘍的藥物,例如次水楊酸鉍(Pepto-Bismol)。

合金:用於焊料、其他一些合金以及冶金添加劑。

鉛替代品:作為鉛的無毒替代品,廣泛應用於陶瓷釉料、魚墜和管道等產品。

化妝品和電子產品:用於某些化妝品和電子產品。

賦存狀態

鉍天然存在,其硫化物和氧化物是重要的商業礦石。

它通常是鉛礦石加工的副產品。

趣聞

鉍是一種氮族元素,與砷和銻具有一些相同的化學性質。

它是元素週期表中最重的元素,被認為是穩定的,儘管從技術上講它具有放射性,半衰期極長。


AI Overview

Bismuth Crystal, Small
Bismuth (Bi) is a heavy, brittle, post-transition metal with atomic number 83, known for being the only non-toxic heavy metalIt is used in over-the-counter medications like Pepto-Bismol to treat digestive issues, as a nontoxic alternative to lead in alloys and other products, and in cosmetics and electronics. Bismuth has a distinctive silver-white metallic luster with an iridescent tarnish, and it is often found as a byproduct of lead ore processing.  
Key Properties 
  • Chemical Symbol: Bi
  • Atomic Number: 83
  • Physical Appearance: A brittle, silver-white metal with a metallic luster and an iridescent tarnish.
  • Density: Heavier than lead.
  • Toxicity: The only non-toxic heavy metal.
  • Melting Point: Has a relatively low melting point compared to other metals.
  • Conductivity: Unusually low thermal and electrical conductivity for a metal.
Uses
  • Medicine: A key ingredient in medications for digestive upset, diarrhea, and ulcers, such as bismuth subsalicylate (Pepto-Bismol). 
  • Alloys: Used in solders, some other alloys, and as a metallurgical additive. 
  • Lead Replacements: Explored as a nontoxic substitute for lead in products like ceramic glazes, fishing sinkers, and plumbing. 
  • Cosmetics & Electronics: Used in some cosmetic products and in electronics. 
Occurrence
  • Bismuth naturally occurs, and its sulfide and oxide forms serve as important commercial ores. 
  • It is often extracted as a byproduct of processing lead ore. 
Interesting Facts
  • Bismuth is a pnictogen and shares some chemical properties with arsenic and antimony. 
  • It is the heaviest element in the periodic table that is considered stable, although it is technically radioactive with an extremely long half-life.